Particle Theory & States of Matter

This lesson covers:

  1. What particle (kinetic) theory is, and what its limitations are
  2. How it explains the 3 states of matter: solid, liquid, and gas
  3. How gaining and losing heat can cause matter to change state

'Forces of attraction' or 'bonds'?


When discussing particle theory, some sources will talk in terms of 'forces of attraction' between the molecules, while others will call them 'bonds'.

For example, as a solid is heated and melts into a liquid, you could say either:


'As the particles vibrate more, some of the forces of attraction between them weaken (or are overcome), causing the solid to melt into a liquid'.


Or:

'As the particles vibrate more, some of the bonds between them break, causing the solid to melt into a liquid'

The key thing to understand here is that if you do use the term 'bonds' in this way, it's not referring to a specific type of bond (e.g. ionic or covalent). When used like this, 'bonds' just means the forces of attraction between particles.

Which theory attempts to explain the three states of matter?

Condensation theory

Particle (kinetic) theory

Nuclear theory

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The particle model (sometimes also called the kinetic model) has 3 main assumptions.


These are that the particles are:

Small

Large

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Inelastic

Elastic

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Cubes

Spheres

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Diagram showing the arrangement of particles in a solid.

heated / cooled / vibrate / liquid / gas / melts / boils


In solids, strong attractive forces hold the particles in place, so that they can only in position.


As the substance is the particles gain energy and vibrate faster and faster. Eventually, the particles have so much energy that they can overcome the forces holding them together and the substance into a .

vibrate
heated
melts
liquid

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Illustration showing solid particles vibrating as energy is transferred to them.

When a solid is heated, energy is transferred to the particles' ________ energy stores, which causes them to vibrate faster.

chemical

kinetic

thermal

elastic

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freeze / boil / melt


As heat is applied to a liquid, the particles gain kinetic energy and move faster. With enough energy they can break the forces of attraction between the molecules. At this point the liquid would into a gas.

boil

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When a gas is heated, the particles gain energy and move faster. 


If the gas is trapped within a container that cannot expand, it means that the of the gas is fixed, and so the inside the container increases. 

kinetic
volume
pressure

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Diagram showing particles in a gas spreading out randomly and then moving closer together to form a liquid when the temperature is lowered.

In gases, the particles have enough energy to overcome the attractive forces between them, and so spread out randomly. 


If the temperature is lowered, they will no longer be able to overcome these attractive forces, and the particles move closer together, and turn into a liquid.


This process is called ________. 

condensation

melting

freezing

boiling

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The temperature at which a solid converts into a liquid is called the point. 


The temperature at which a liquid converts into a gas is called the point. 

melting
boiling

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Illustration showing a solid ice cube, a liquid water droplet, and a gas cloud representing the three states of matter.

Which state of matter matches each of the descriptions below?


Solid / Liquid / Gas


  1. Strong forces of attraction between particles:
  2. Weak forces of attraction between particles:
  3. Very weak forces of attraction between particles:
Solid
Liquid
Gas

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Illustration of a Bunsen burner with a flame heating gas.

When a gas is heated, which of the following statements are true?

(Select all that apply)

If it's in a fixed container the volume will increase

If it's in a fixed container the pressure will increase

If it's in an expandable container the volume will increase

If it's in an expandable container the pressure will increase 

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In a closed system, changes in state won't change the mass at all.


Why is this the case?

The bonds between the particles remain the same

The velocity of the particles remain the same

The number of particles remains the same

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Which state has the lowest density?

Liquids

Solids

Gases

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Illustration of particles arranged in a regular lattice structure representing a solid state of matter.

"Particles are arranged in a regular lattice structure and can only vibrate in place."


Which state of matter does this describe?

Liquid

Gas

Solid

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"When heat is lost, the particles won't have enough energy to overcome forces of attraction. Thus, bonds start to form between the particles."


Which change of state does this describe?

Boiling

Melting

Condensing

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