Percentage Yield

This lesson covers: 

1. What theoretical yield is and how to calculate it
2. Why actual yield is always less than theoretical yield
3. How percentage yield is calculated

Theoretical yield is the maximum possible

The theoretical yield of a chemical reaction is the maximum mass of product that could be produced, assuming the reaction goes perfectly with no loss of chemicals.

To calculate the theoretical yield, follow these steps:

1. Use a balanced chemical equation to find the mole ratio between reactants and products.
2. Calculate the moles of the limiting reagent present.
3. Determine the mass of product that these moles of limiting reagent could produce, using the mole ratio.

For example, in the reaction:

C₂H₅OH + [O] ➔ CH₃CHO + H₂O

The C₂H₅OH : CH₃CHO mole ratio is 1 : 1.

So if 0.300 mol (13.8 g) of C₂H₅OH is present and [O] is in excess, the theoretical yield of CH₃CHO is 0.300 mol (13.2 g).

Actual yield is always less than theoretical

The actual yield is the mass of product actually produced and collected from a reaction.

The actual yield is always lower than the theoretical yield because of several factors:

• Some starting material may not react completely.
• Products can be lost during workup procedures, such as filtering or transferring between containers.
• Side reactions may occur, reducing the yield of the desired product.

For the example reaction, if only 5.94 g of CH₃CHO was collected, this is the actual yield, which is less than the theoretical yield of 13.2 g.

Calculating percentage yield

Percentage yield is a measure of how efficient a reaction is, indicating how close the actual yield is to the theoretical maximum.

To calculate it, use the formula:

% yield=theoretical yieldactual yield​×100

For the example reaction:

% yield=13.25.94​×100=45.0%

The percentage yield offers valuable insights:

• A yield above 90% is seen as efficient and high-yielding.
• Lower yields suggest that the process needs optimisation.

Worked example 1 - Calculating actual yield

The balanced chemical equation for the synthesis of ammonia (NH₃) through the Haber process is: N₂ + 3H₂ ➔ 2NH₃

Calculate the actual mass (in g) of ammonia produced given a theoretical yield of ammonia of 34.0 g and a percentage yield of 77.7%.

Step 1: Rearrange equation

Actual yield =100percentage yield​× theoretical yield

Step 2: Substitution and correct evaluation

Actual yield =10077.7​×34.0=26.4 g

Worked example 2 - Calculating theoretical yield and percentage yield

The balanced chemical equation for the synthesis of water from hydrogen and oxygen gas is: 2H₂ + O₂ ➔ 2H₂O

Calculate the percentage yield of this reaction if 2.00 g of hydrogen reacts with excess oxygen to produce 14.5 g of water.

Step 1: Calculate number of moles of H₂

n =Mr ​m​=2.02.00​=1.00 mol

Step 2: Calculate number of moles of H₂O

H₂ : H₂O mole ratio = 2:2 = 1:1

Moles of H₂O = 1.00 mol

Step 3: Calculate theoretical yield

m = n x M_r = 1.00 x 18.0 = 18.0 g

Step 4: Equation

Percentage yield =theoretical yieldactual yield​×100

Step 5: Substitution and correct evaluation

Percentage yield =18.014.5​×100=80.6%