How are emission lines produced?

When electrons de-excite they emit photons of discrete frequencies.

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What causes discrete emission lines?

Electrons are in quantised energy levels.

When electrons de-excite between these energy levels, only photons of certain frequencies are emitted.

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What causes absorption lines?

When a continuous spectrum of light is passed through a gas, discrete wavelengths of light are absorbed to excite electrons in the gas.

This results in dark lines corresponding to the absorbed wavelengths in the line absorption spectra.

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State the equation linking photon energy (E), frequency (f) and the different between energy levels E1 and E2

E = hf = ΔE = E1 − E2


E = photon energy (J)

h = Plank's constant = 6.63 x 10-34  (J s)

f = frequency (Hz)

ΔE = difference between energy levels (J)

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Do emission spectra of the same element always look the same?

Yes. 


Each element has it's own set of discrete energy levels which correspond to the wavelengths of light emitted.

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What is a continuous spectrum of light?

Light emitted across a continuous range of wavelengths.

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