What is an acid-base indicator?

An acid-base indicator is a weak acid that changes colour in response to changes in pH. It is used to determine the end point of a titration.

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What is a pH titration curve?

A pH titration curve is a graphical representation of how the pH of a solution changes as an acid or base is added during a titration.

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What is the equivalence point of a titration?

The equivalence point of a titration is the point at which the moles of acid and base are stoichiometrically equivalent, resulting in complete neutralisation.

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What are the shapes of the pH titration curves for the following combinations of acid and base?

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How does the pH titration curve change when an acid is added to a base?

The shape of the pH titration curve stays the same but it is flipped vertically as shown in the graphs above.


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What criteria guide the selection of an appropriate indicator for a titration?

The indicator should give a sudden and distinct colour change within a suitable pH range close to the equivalence point, i.e. the pH range of the indicator should coincide with the vertical section of the titration curve.

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HA ⇌ H+ + A-

Explain, in terms of the equilibrium above, the colour change of an acid-base indicator (HA) when a basic solution containing OH- ions is added.

Upon addition of a basic solution containing OH- ions:

  1. OH- ions from the base react with H+ ions in the indicator.
  2. The position of equilibrum shifts to the right.
  3. The colour of the solution changes to the colour of A-.

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Explain the colour of an acid-base indicator (HA) at the end point of a titration.

At the end point of a titration, the solution contains equal concentrations of HA and A- so the colour of the indicator will be in between the colours of HA and A-.

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Why is no indicator suitable for titration between a weak acid and a weak base?

No indicator is suitable because there is no sharp change in pH at the equivalence point.

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How is a pH meter calibrated?

A pH meter is calibrated by adjusting the meter's readings to match known pH values of standard solutions.

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HA ⇌ H+ + A-

Explain, in terms of the equilibrium above, the colour change of an acid-base indicator (HA) when an acidic solution containing H+ ions is added.

Upon addition of an acidic solution containing H+ ions:

  1. H+ ions from the acid react with A- ions from the indicator.
  2. The position of equilibrum shifts to the left.
  3. The colour of the solution changes to the colour of HA.

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What is the end point of an acid-base titration?

The endpoint is the point at which the reaction between the acid and base is complete.

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