What is the general formula for alcohols?

CnH2n+1OH


You may also see the general formula of alcohols written as CH2n+2O.

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What is the functional group of alcohols?

-OH 


-OH is called a hydroxyl group.

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Explain how alcohols can be classified as primary, secondary or tertiary based on their structure.

  • Primary: -OH group attached to a carbon with one other alkyl group (or no alkyl groups).
  • Secondary: -OH group attached to a carbon with two other alkyl groups.
  • Tertiary: -OH group attached to a carbon with three other alkyl groups.

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State and explain the difference in acidity between ethanol and water.

Ethanol is less acidic than water.


This is due to the positive inductive effect of the ethyl group which concentrates more negative charge on the oxygen of the C2H5Oion than the hydrogen atom does in the OH- ion. This means that the C2H5O- ion accepts a proton more readily than the OHion.


The equilibrium for the dissociation of ethanol, C2H5OH ⇌ H+ + C2H5O-, lies further to the left than the equilbrium for the dissociation of water, H2O ⇌ H+ + OH-.

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Outline 5 types of reaction that can be used to produce alcohols.

  1. Electrophilic addition of alkenes with steam in the presence of a H3PO4 catalyst.
  2. Oxidation of alkenes with cold dilute aqueous KMnO4 to form a diol. 
  3. Substitution of a halogenoalkane using aqueous alkali e.g. NaOH.
  4. Reduction of an aldehyde, ketone or carboxylic acid using a reducing agent e.g. NaBH4 or LiAlH4.
  5. Hydrolysis of an ester using dilute acid or dilute alkali and heat.

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Why are alcohols polar molecules?

Alcohols are polar molecules because they contain a polar O-H bond. This polarity arises from the difference in electronegativity between oxygen and hydrogen atoms.

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What is the strongest type of intermolecular force in alcohols?

Hydrogen bonding


Induced dipole-dipole forces and permanent dipole-dipole forces are also present in alcohols, but are weaker than hydrogen bonding.

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