What is an allotrope?

Allotropes are different structural forms of the same element in the same physical state.


For example, diamond, graphite and graphene are allotropes of each other because they are all solid carbon.

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Why can graphite be used as a lubricant?

  1. Carbon atoms are arranged in layers.
  2. The forces between layers are weak intermolecular forces.
  3. This means they don't need much energy to break, so layers slide over each other easily.

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What are the properties of graphite?

  1. Soft and slippery.
  2. Conducts electricity along layers.
  3. Lower density than diamond.
  4. High sublimation temperature but lower melting point than diamond.

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Can graphite conduct electricity? Explain why.

Graphite can conduct electricity because it has delocalised electrons that can flow and carry charge.

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Describe the structure and bonding of graphite.

Graphite has a giant covalent lattice structure.


Each carbon is covalently bonded to 3 other carbon atoms, forming a sheet of hexagonal rings. The separate sheets are held together by intermolecular forces. It also has delocalised electrons that can flow throughout the structure. 

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In graphite, how many covalent bonds does each carbon atom have?

3

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Explain why diamond can't conduct electricity.

Diamond can't conduct electricity because all of carbon's outer electrons are involved in bonding so there are no free electrons to carry charge.

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Describe the structure of and bonding of diamond.

Diamond has a giant covalent lattice structure.


Each carbon is covalently bonded to 4 other carbon atoms in a tetrahedral arrangement.

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In diamond, how many bonds does each carbon atom have?

4


The carbon atoms at the edge haven't had all their bonds drawn - look at the atoms in the middle to see the 4 bonds.

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What are giant covalent structures?

Giant covalent structures are an extensive interconnecting networks of covalently bonded atoms, involving huge lattices extending in three dimensions.

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What was the first fullerene to be discovered?

Buckminsterfullerene


Buckminsterfullerene has the molecular formula C60.

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What are fullerenes?

Fullerenes are spherical or tubular molecules of carbon atoms.

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Why do giant covalent structures have high melting points?

They have many strong covalent bonds between atoms which require a lot of energy to break.

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