What is the purpose of a catalytic converter in a car?

To convert harmful exhaust gases into less harmful gases before they are released into the atmosphere.

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Which transition metals are used in catalytic converters?

Catalytic converts use platinum, rhodium, and palladium catalysts.

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What is a homogeneous catalyst?

A catalyst that has the same physical state as the reactants.


For example, sulfuric acid is a homogeneous catalyst in the production of esters because sulfuric acid and the reactants (an alcohol and a carboxylic acid) are all liquids.

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What is a heterogeneous catalyst?

A catalyst that has a different physical state from the reactants.


For example, iron is a heterogeneous catalyst in the Haber process because iron is a solid and the reactants (N2 and H2) are gases.

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Outline the steps involved in the heterogeneous catalysis facilitated by iron during the Haber process.

  1. Diffusion of N2 and H2 towards the iron catalyst
  2. Adsorption of N2 and H2 onto the iron surface.
  3. Formation of new bonds between N and H atoms, forming NH3.
  4. Desorption of NH3 from the iron surface.
  5. Diffusion of NH3 away from the iron catalyst.

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What is the equation for the catalytic removal of nitrogen monoxide (NO) and carbon monoxide (CO) from the exhaust gases of car engines?

NO + CO ➔ 1⁄2N2 + CO2

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Identify the type of catalyst (homogeneous or heterogeneous) in each of the following examples:

  1. Iron in the Haber process.
  2. Nitrogen oxides in the oxidation of sulfur dioxide.
  3. Platinum in catalytic converters.
  4. Fe2+ ions in the iodine-peroxodisulfate reaction.
  1. Iron in the Haber process - heterogeneous.
  2. Nitrogen oxides in the oxidation of sulfur dioxide - homogeneous.
  3. Platinum in catalytic converters - heterogeneous.
  4. Fe2+ ions in the iodine-peroxodisulfate reaction - homogeneous.

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Explain, with the use of equations, how Fe3+ ions catalyse the following reaction:

S2O82- + 2I- ➔ 2SO42- + I2

Fe3+ ions catalyse this reaction by participating in two redox reactions:

  1. Reduction of Fe3+ to Fe2+ by I-:

2Fe3+ + 2I- ➔ 2Fe2+ + I2

  1. Oxidation of Fe2+ back to Fe3+ by S2O82-:

2Fe2+ + S2O82- ➔ 2Fe3+ + 2SO42-


The overall reaction is catalysed by both Fe2+ and Fe3+ so the redox reactions can take in either order.

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Which species can catalyse the reaction between S2O82- and I- ions?

Fe2+ or Fe3+ ions

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What is the equation for the catalytic removal of nitrogen dioxide (NO2) and carbon monoxide (CO) from the exhaust gases of car engines?

NO2 + 2CO ➔ 1⁄2N2 + 2CO2

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