What 4 pieces of information does a proton NMR spectrum reveal about the carbon environments in an organic compound?

A proton NMR spectrum reveals:

  1. The number of proton environments.
  2. The types of proton environment present.
  3. The relative numbers of each type of proton.
  4. The number of non-equivalent protons adjacent to a given proton.

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How can you work out the number of proton environments in a molecule from its 1H NMR spectrum?

The number of peaks in the 1H NMR spectrum corresponds to the number of unique proton environments in the molecule.

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How can you work out the types of proton environment present in a molecule from its 1H NMR spectrum?

The chemical shift range that a peak appears in indicates the type of proton environment. Different ranges correspond to different functional groups.

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What information do spin-spin splitting patterns provide?

Spin-spin splitting patterns reveal the number of non-equivalent protons on adjacent carbon atoms.

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What is the n + 1 rule?

For a proton with n protons attached to an adjacent carbon atom, the number of sub-peaks in a splitting pattern = n + 1


For example, a peak split into three (i.e. a triplet) indicates there are two hydrogens on the neighbouring carbon atom. 

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What is a deuterated solvent?

A deuterated solvent is one in which the 1H atoms have been replaced by 2H atoms.


The 2H isotope of hydrogen is called deuterium (D).

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Explain why deuterated solvents are used in 1H NMR spectroscopy.

The 1H atoms in a regular solvent produce signals that can interfere with the spectrum of the sample being analysed.

Deuterium does not produce any signal in the frequency ranges used for 1H, so this interference is prevented and a higher resolution of the sample's spectrum can is obtained.


CDCl3 is a commonly used deuterated solvent in NMR spectroscopy.

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Why are 1H NMR spectra more complex than 13C NMR spectra?

1H NMR spectra are more complex than 13C NMR spectra due to the presence of spin-spin coupling between hydrogen atoms which causes NMR peaks to split into sub-peaks.

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How can you work out the relative numbers of each type of proton present in a molecule from its 1H NMR spectrum?

The relative peak areas are proportional to the relative numbers of equivalent protons producing each signal.

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