Question 1
Chlorine is added to 2 cm3 of a dilute solution of potassium iodide.
The equation for the reaction between chlorine and iodide ions is
Cl2(aq) + 2I-(aq) ➔ I2(aq) + 2Cl-(aq)
Which statement is correct?
iodide ions oxidise chlorine
iodide ions reduce chlorine
chlorine reduces iodide ions
chlorine is neither oxidised nor reduced
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Question 2
Redox reactions occur very frequently in the chemistry of group VII.
Which statement is correct?
chlorine will oxidise bromide ions but not iodide ions
fluorine is the weakest oxidising agent out of F2, Cl2, Br2 and I2
iodide ions are the weakest reducing agent out of F-, Cl-, Br- and I-
when chlorine reacts with water, chlorine is both oxidised and reduced
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Question 3
Chlorine gas is widely used to treat contaminated water.
Which species present in water when chlorine gas has been added is responsible for killing bacteria?
ClO2-
Cl-
HCl
OCl-
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Question 4
Why do the boiling points of the halogens increase down the group?
there is an increase in bond enthalpy
there is an increase in bond polarity
there is an increase in the strength of instantaneous dipoles
there is a decrease in electronegativity
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Question 5
Which statement about the reactions of halogens with halide ions is correct?
I2(aq) can oxidise Br-(aq)
Cl2(aq) can reduce Br-(aq)
Br-(aq) can reduce Cl2(aq)
Cl-(aq) can oxidise I2(aq)
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Question 6
Chlorine reacts with cold, dilute, aqueous sodium hydroxide.
Which is a complete list of the products?
sodium chloride, sodium chlorate(I) and water
sodium chlorate(I) and water
sodium chloride, sodium chlorate(V) and water
sodium chloride and sodium chlorate(I)
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Question 7
Which property increases down group 7?
ability to oxidise a given reducing agent
boiling point
electronegativity
first ionisation energy
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Question 8
Which equation shows a redox reaction that does not occur?
Br2(aq) + 2KI(aq) ➔ I2(aq) + 2KBr(aq)
Cl2(g) + 2KI(aq) ➔ I2(aq) + 2KCl(aq)
Cl2(g) + 2KBr(aq) ➔ Br2(aq) + 2KCl(aq)
I2(aq) + 2KBr(aq) ➔ Br2(aq) + 2KI(aq)
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Question 9
What is the best oxidising agent?
F2
F-
I2
I-
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